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The moisturizer forms a sort of a protective cap, which seals all the previous steps. While sealing moisture, it also pulls it from the inner to the outer layers of the skin, thus maintaining skins’ moisture barrier.
Very generally speaking, emulsions, lotions and gels are “lighter” forms of creams – they are usually water-based and best suited for oily, dehydrated, combination and troubled skin.
While creams usually contain more oil and are more convenient for dry and mature skin.